📘 ❞ Pericyclic Reaction ) Oxford Chemistry Primers 67) ❝ كتاب ــ كاتب غير معروف

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█ _ كاتب غير معروف 0 حصريا كتاب Pericyclic Reaction ) Oxford Chemistry Primers 67) 2024 67): reaction the third type of organic mechanism along with ionic and radical reactions include some most powerful synthetically useful reactions, like Diels Alder reaction, 1,3 dipolar cycloadditions, ene Claisen rearrangements, 2,3 Wittig rearrangement, diimide reduction, sulfoxide elimination many others These are characterised by having cyclic transition structures, also have highly predictable stereochemical features Every chemist must be able to recognize various types pericyclic know something their mechanisms factors that affect how well they work in synthesis This book identifies four main classes discusses characteristics important class, cycloadditions providing a working knowledge, based on real examples, scope, patterns reactivity, stereochemistry Then it explains using ideas molecular orbital theory, but ( as companion A J Kirby Stereoelectronic Effects without mathematics It presents Woodward Hoffmann rules form two all encompassing rules, one for thermal its opposite photochemical explained detail carefully illustrated, so you will predict outcome any The remaining chapters use this theoretical framework show other three electrocyclic sigmatropic rearrangements group transfer By end book, recognise confidence whether is allowed, what stereochemistry, knowledge range available synthetic كتب التكنولوجيا والعلم مجاناً PDF اونلاين مصدر المعرفة التي تُكرَّس من أجل صناعة الأدوات ومُعالجة الأنشطة واستخراج الموادّ لعِلْـمُ هو بحث ظواهر معينة لبيان حقيقتها وعناصرها ونشأتها وتطورها ووظائفها وعلاقاتها وقوانينها وهو كل نوع العلوم والمعارف والأفكار والتطبيقات فى الكيمياء والفيزياء والجيولوجيا والرياضيات والأحياء تكنولوجيا المعلومات وعلم الحاسوب وعلاقة العلم بالتكنولوجيا Technology source devoted making tools, treating activities, extracting materials science research specific phenomena reality, elements, origins, evolution, functions, relationships, laws every kind science, ideas, applications He wrote books chemistry, physics, geology, mathematics, biology, information technology, computer relationship technology

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Pericyclic Reaction ) Oxford Chemistry Primers 67)
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Pericyclic Reaction ) Oxford Chemistry Primers 67)

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Pericyclic Reaction ) Oxford Chemistry Primers 67)
كتاب

Pericyclic Reaction ) Oxford Chemistry Primers 67)

ــ كاتب غير معروف

عن كتاب Pericyclic Reaction ) Oxford Chemistry Primers 67):
Pericyclic reaction - the third type of organic reaction mechanism along with ionic and radical reactions - include some of the most powerful synthetically useful reactions, like the Diels - Alder reaction, 1,3- dipolar cycloadditions, the Alder ene reaction, Claisen rearrangements, the 2,3-Wittig rearrangement, diimide reduction, sulfoxide elimination and many others. These reactions are characterised by having cyclic transition structures, and also have highly predictable stereochemical features. Every organic chemist must be able to recognize the various types of pericyclic reaction and know something of their mechanisms and the factors that affect how well they work in organic synthesis. This book identifies the four main classes of pericyclic reaction, and discusses the main characteristics of the most important class, cycloadditions - providing a working knowledge, based on real examples, of their scope, patterns of reactivity, and stereochemistry. Then it explains the main features using ideas based in molecular orbital theory, but ( as in the companion book by A. J. Kirby on Stereoelectronic Effects ) without mathematics. It presents the Woodward - Hoffmann rules in the form of two all-encompassing rules, one for thermal reactions and its opposite for photochemical reactions. These rules are explained in detail and carefully illustrated, so that you will be able to predict the stereochemical outcome for any pericyclic reaction. The remaining chapters use this theoretical framework to show how the rules work with the other three classes of pericyclic reactions - electrocyclic reactions, sigmatropic rearrangements and group transfer reactions. By the end of the book, you will be able to recognise any pericyclic reaction and predict with confidence whether it is allowed, and with what stereochemistry, and you will have a working knowledge of the range of pericyclic reactions available to the synthetic organic chemist.


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